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Dielectric behavior and impedance spectroscopy in lead-free

The maximum energy-storage density of all the samples reached 1.1–1.4 J/cm 3, accompanied with good temperature stability in the range of 25–140 °C. These results indicate that (BNT–xBT)–NBN system should be a promising lead-free material for energy-storage capacitor applications.

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Enhanced breakdown strength and energy storage density of lead-free

Development of lead-free ceramics with sufficient energy storage density is the main challenge for dielectric energy storage ceramics. Up to now, extensive investigations have illustrated that the excellent performances of a capacitor depend on the high dielectric breakdown strength (BDS), high maximum polarization ( P max ) and low

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Design strategies of high-performance lead-free electroceramics

This review briefly discusses the energy storage mechanism and fundamental characteristics of a dielectric capacitor, summarizes and compares the state

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Recent advances in lead-free dielectric materials for energy storage

Relaxor/antiferroelectric composites: a solution to achieve high energy storage performance in lead-free dielectric ceramics. Recently developed Na1/2Bi1/2TiO3 (NBT)-based relaxor ferroelectric ceramics are promising lead-free candidates for dielectric energy storage applications because of their non-toxicity and.

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Significantly Improvement of Comprehensive Energy Storage Performances

1. Introduction. The development of efficient and high-performance materials for electrical energy storage and conversion applications, including of mobile electronic devices, hybrid electric vehicles, and military, has become a must to meet an ever-increasing need for electrical energy [1], [2], [3].Among tools developed for this

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Polymorphic Heterogeneous Polar Structure Enabled Superior Capacitive Energy Storage in Lead‐Free

High-performance energy storage dielectrics capable of low/moderate field operation are vital in advanced electrical and electronic systems. However, in contrast to achievements in enhancing recoverable energy density (W rec), the active realization of superior W rec and energy efficiency (η) with giant energy-storage coefficient (W rec

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[PDF] Perspectives and challenges for lead-free energy-storage

Emerging applications of energy-storage MLCCs are then discussed in terms of advanced pulsed power sources and high-density power converters from a theoretical and technological point of view. Finally, the challenges and future prospects for industrialization of lab-scale lead-free energy-storage MLCCs are discussed.

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Review on energy storage in lead‐free ferroelectric films

However, due to materials limitations and their preparation requirements, there are significant challenges which limit the use of current dielectrics in high-energy storage capacitors. In addition material limitations such as, low dielectric permittivity, low breakdown strength, and high hysteresis loss decrease these materials'' energy density

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Lead-Free NaNbO3-Based Ceramics for Electrostatic Energy Storage

The burgeoning significance of antiferroelectric (AFE) materials, particularly as viable candidates for electrostatic energy storage capacitors in power electronics, has sparked substantial interest. Among these, lead-free sodium niobate (NaNbO3) AFE materials are emerging as eco-friendly and promising alternatives to lead

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Giant energy-storage density with ultrahigh efficiency in lead-free

A giant W rec ~10.06 J cm −3 with an ultrahigh η ~90.8% is realized in lead-free relaxor ferroelectrics, which is the optimal comprehensive energy storage

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Tailoring ferroelectric polarization and relaxation of BNT-based lead

Ultrahigh dielectric breakdown strength and excellent energy storage performance in lead-free barium titanate-based relaxor ferroelectric ceramics via a combined strategy of composition modification, viscous polymer processing, and liquid-phase sintering. Chem. Eng. J., 398 (2020), Article 125625.

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Recent advances in lead-free dielectric materials for energy

We discuss and analyze the energy-storage properties of these materials to provide guidance for the design of new lead-free dielectric materials with high energy

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Progress and outlook on lead-free ceramics for energy storage

Among various energy conversion and storage systems, lead-free ceramic dielectric capacitors emerge as a preferred choice for advanced pulsed power devices

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Stress-induced tailoring of energy storage properties in lead-free

In this study, the stress-modulated energy storage properties of lead-free polycrystalline Ba 0.85 Ca 0.15 Zr 0.1 Ti 0.9 O 3 was investigated as a function of temperature from 25 °C to 55 °C. The externally applied uniaxial compressive stress of −160 MPa increased the recoverable energy storage density by 226% to a maximum value of

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Realizing Outstanding Energy Storage Performance in KBT‐Based Lead‐Free

The great potential of K 1/2 Bi 1/2 TiO 3 (KBT) for dielectric energy storage ceramics is impeded by its low dielectric breakdown strength, thereby limiting its utilization of high polarization. This study develops a novel composition, 0.83KBT-0.095Na 1/2 Bi 1/2 ZrO 3-0.075 Bi 0.85 Nd 0.15 FeO 3 (KNBNTF) ceramics, demonstrating

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Giant comprehensive capacitive energy storage in lead-free quasi

Dielectric ceramic capacitors have shown extraordinary promise for physical energy storage in electrical and electronic devices, but the major challenge of

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A review on the development of lead-free ferroelectric energy

In this review, we comprehensively summarize the research progress of lead-free dielectric ceramics for energy storage, including ferroelectric ceramics, composite ceramics, and

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Energy storage performance of silicon-integrated epitaxial lead-free

Ultrahigh energy storage in lead-free BiFeO 3 /Bi 3.25 La 0.75 Ti 3 O 12 thin film capacitors by solution processing Appl. Phys. Lett., 112 (2018), Article 033904 View in Scopus Google Scholar [16] M.S. Alfonso, C. Lapeyronie, M. Goubet, B. Viala, J.H. Tortai

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BaTiO3-based lead-free relaxor ferroelectric ceramics for high energy storage

Fig. 6 (e) illustrates the energy storage performance of BT, NN, KNN, BNT, and BFO-based lead-free energy storage ceramics reported in recent years (further information is presented in Table S1). Fig. 6 (e) presents that there are very few BT-based ceramics with W rec > 6.0 J cm −3 and E b > 700 kV cm −1 .

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Perovskite lead-free dielectrics for energy storage applications

In this review, we summarize the principles of dielectric energy-storage applications, and recent developments on different types of dielectrics, namely linear dielectrics, paraelectrics, ferroelectrics, and antiferroelectrics, are surveyed, focusing on

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Review of lead-free Bi-based dielectric ceramics for energy

Therefore, lead-free dielectric energy-storage ceramics with high energy storage density have become a research hot spot. In this paper, we first present the

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Recent developments in BaTiO3 based lead-free materials for energy storage

Lead-free ferroelectric ceramics, such as MgO, YNbO 4, BiFeO 3, and Bi 0.5 Na 0.5 TiO 3, etc. are few materials that have been repeatedly combined with BT to improve electrical, magnetic, multiferroic, and energy

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A review on the development of lead-free ferroelectric energy-storage

Energy storage materials and their applications have attracted attention among both academic and industrial communities. Over the past few decades, extensive efforts have been put on the development of lead-free high-performance dielectric capacitors. In this review, we comprehensively summarize the research Journal of Materials Chemistry C

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Large Electrocaloric Responsivity and Energy Storage Response in

Such electrocaloric responsivity significantly exceeds those obtained so far in other barium titanate-based lead-free electrocaloric ceramic materials. Energy storage investigations show promising results: stored energy density of ~17 mJ/cm3 and an energy efficiency of ~88% in the composition BTG5.

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Improved energy storage performance of lead-free

BaTiO 3 (BT) ceramics with excellent energy storage performance (ESP) are in great demand in the power electronics industry due to their high power density. However, the traditional BT-based ceramics cannot simultaneously achieve high breakdown strength and high maximum polarization. Here, we bring forth ideas of design strategy to

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Achieving outstanding temperature stability in KNN-based lead-free

Lead-free ceramics with prominent energy storage properties are identified as the most potential materials accessed in the dielectric capacitors. Nevertheless, high recoverable energy storage density ( W rec ), large energy storage efficiency ( η ) and preferable temperature stability can hardly be met simultaneously.

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Sm doped BNT–BZT lead-free ceramic for energy storage

Dielectric ceramics with good temperature stability and excellent energy storage performances are in great demand for numerous electrical energy storage applications. In this work, xSm doped 0.5Bi0.51Na0.47TiO3–0.5BaZr0.45Ti0.55O3 (BNT–BZT − xSm, x = 0–0.04) relaxor ferroelectric lead-free ceramics were synthesized

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Bi0·5K0·5TiO3-based lead-free relaxor ferroelectric with high energy

1. Introduction. For a long time, lead-containing materials (such as PbZrO 3) have been diffusely used in the fields of energy storage with their excellent performance [1].However, as the EU and other countries tighten their policies on lead-containing electronic products, the development of lead-free dielectric materials is becoming an

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Domain engineered lead-free Bi0.5Na0.5TiO3-Bi(Ni0.5Hf0.5)O3

Lead-free materials for energy storage are increasingly receiving attention due to their exceptional properties of high charging and discharging rates, high power density, and eco-friendliness. In this work, (1− x )Bi 0.5 Na 0.5 TiO 3 - x Bi(Ni 0.5 Hf 0.5 )O 3 (BNT-BNH, x = 0.05, 0.10, 0.15 and 0.20) ceramics were prepared for

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BaTiO3-based lead-free relaxor ferroelectric ceramics for high energy

Fig. 6 (e) illustrates the energy storage performance of BT, NN, KNN, BNT, and BFO-based lead-free energy storage ceramics reported in recent years (further information is presented in Table S1). Fig. 6 (e) presents that there are very few BT-based ceramics with W rec > 6.0 J cm −3 and E b > 700 kV cm −1.

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